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  • Title: Silver-promoted domino Pd-catalyzed amination/direct arylation: access to polycyclic heteroaromatics.
    Author: Bryan CS, Lautens M.
    Journal: Org Lett; 2008 Oct 16; 10(20):4633-6. PubMed ID: 18800841.
    Abstract:
    Novel tetracyclic and pentacyclic indole derivatives can be prepared from readily available gem-dibromovinyl substrates in a single step by means of an efficient Pd-catalyzed domino Buchwald-Hartwig amination/direct arylation reaction. Enhanced reactivity and selectivity are obtained by the addition of silver salts.
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