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  • Title: Carborane-based metal-organic frameworks as highly selective sorbents for CO(2) over methane.
    Author: Bae YS, Farha OK, Spokoyny AM, Mirkin CA, Hupp JT, Snurr RQ.
    Journal: Chem Commun (Camb); 2008 Sep 21; (35):4135-7. PubMed ID: 18802507.
    Abstract:
    Separation of CO(2)/CH(4) mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO(2) over CH(4) ( approximately 17) are obtained, especially in the material with open metal sites.
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