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  • Title: A structural, spectroscopic and computational study of the molecular and electronic structure of a [bis(alpha-diiminato)manganese(II)] pi radical complex.
    Author: Ghosh M, Weyhermüller T, Wieghardt K.
    Journal: Dalton Trans; 2008 Oct 14; (38):5149-51. PubMed ID: 18813366.
    Abstract:
    The synthesis, molecular and electronic structure of the first bis(alpha-diiminato)manganese(II) complex are reported, [Mn(II)(L )(2)] (S(t) = (3)/(2)) where (L )(1-) represents the one-electron reduced form of N,N'-bis(2,6-isopropylphenyl)-1,4-diaza-1,3-diene; density functional theoretical calculations using the B3LYP functional and the broken symmetry approach BS(5,2) corroborate the presence of a high-spin Mn(II) ion and two ligand pi radical monoanions.
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