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  • Title: Tandem palladium-catalyzed N,C-coupling/carbonylation sequence for the synthesis of 2-carboxyindoles.
    Author: Vieira TO, Meaney LA, Shi YL, Alper H.
    Journal: Org Lett; 2008 Nov 06; 10(21):4899-901. PubMed ID: 18826321.
    Abstract:
    Tandem palladium-catalyzed N,C-coupling/carbonylation, under 10 atm of carbon monoxide and at 110 degrees C, is a novel and efficient method for the preparation of 2-carboxyindoles. The catalyst system tolerates a variety of functional groups, and the noted indoles were obtained in good isolated yields.
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