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Title: Total syntheses of (+/-)-montanin A and (+/-)-teuscorolide. Author: Chen IC, Wu YK, Liu HJ, Zhu JL. Journal: Chem Commun (Camb); 2008 Oct 21; (39):4720-2. PubMed ID: 18830471. Abstract: The first total syntheses of (+/-)-montanin A and (+/-)-teuscorolide have been achieved from an advanced precursor previously developed via a Diels-Alder strategy; in the synthetic sequence, the synthesis of montanin A was first accomplished in 8 steps, from which teuscorolide was readily achieved in 2 steps by using a novel furan oxidative cyclization-retro-cyclization process as a key operation.[Abstract] [Full Text] [Related] [New Search]