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  • Title: Probing interactions by means of pulsed field gradient nuclear magnetic resonance spectroscopy.
    Author: Cozzolino S, Sanna MG, Valentini M.
    Journal: Magn Reson Chem; 2008; 46 Suppl 1():S16-23. PubMed ID: 18855336.
    Abstract:
    Molecular self-diffusion coefficients (D) of species in solution are related to size and shape and can be used for studying association phenomena. Pulsed field gradient nuclear magnetic resonance (PFG-NMR) spectroscopy has been revealed to be a powerful analytical tool for D measurement in different research fields. The present work briefly illustrates the use of PFG-NMR for assessing the existence of interactions in very different chemical systems: organic and organometallic compounds, colloidal materials and biological aggregates. The application of PFG-NMR is remarkable for understanding the role of anions in homogenous transition metal catalysis and for assessing the aggregation behaviour of biopolymers in material science.
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