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  • Title: Formation of a bridging-imido d6 rhodium compound by nitrene capture. insertion and cycloaddition reactions.
    Author: Tejel C, Ciriano MA, Jiménez S, Passarelli V, López JA.
    Journal: Inorg Chem; 2008 Nov 17; 47(22):10220-2. PubMed ID: 18855386.
    Abstract:
    The first d (6) rhodium imido complex, [{(C 5Me 5)Rh(mu-NSO 2C 6H 4Me- p)} 2] ( 2), has been obtained from the reaction of [(C 5Me 5)Rh(C 2H 4) 2] with chloramine-T. Carbon monoxide inserts into the N-Rh bonds in 2 to give the dinuclear ureylene complex [(C 5Me 5)Rh(mu-{(Ts) N-CO-N(Ts)}Rh(CO)(C 5Me 5)], while the azide C 6F 5N 3 adds to 2 to give the mononuclear tetrazene complex [(C 5Me 5)Rh{( p-MeC 6H 4SO 2)N 4(C 6F 5)}].
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