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  • Title: Soil column experiments used as a means to assess transport, sorption, and biodegradation of pesticides in groundwater.
    Author: Magga Z, Tzovolou DN, Theodoropoulou MA, Dalkarani T, Pikios K, Tsakiroglou CD.
    Journal: J Environ Sci Health B; 2008 Nov; 43(8):732-41. PubMed ID: 18941999.
    Abstract:
    Soil column experiments are used to investigate the fate of three pesticides of high, intermediate, and low solubility in groundwater: N- phosphonomethyl glycine (glyphosate); O,O-diethyl-S-[(ethylthio)methyl]phosphorodithioate (phorate); (2,4-dichlorophenoxy)acetic acid (2,4-D). Feed solutions are prepared by adding each pesticide (100 mg/L glyphosate, 50 micro g/L phorate, 50 mg/L 2,4-D) along with conservative tracer, KBr, in synthetic groundwater. The concentration of the pesticides in effluents is detected by ion chromatography (glyphosate, 2,4-D) and GC-FID (phorate). The Br(-) breakthrough curves are employed to estimate the dispersion coefficient and mean pore velocity in each column. Solute transport and reactive models accounting for equilibrium/non-equilibrium sorption and biodegradation are coupled with inverse modeling numerical codes to estimate the kinetic parameters for all pesticides.
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