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Title: Structural and magnetic phase diagram of CeFeAsO(1- x)F(x) and its relation to high-temperature superconductivity. Author: Zhao J, Huang Q, de la Cruz C, Li S, Lynn JW, Chen Y, Green MA, Chen GF, Li G, Li Z, Luo JL, Wang NL, Dai P. Journal: Nat Mater; 2008 Dec; 7(12):953-9. PubMed ID: 18953342. Abstract: Recently, high-transition-temperature (high-Tc) superconductivity was discovered in the iron pnictide RFeAsO(1-x)F(x) (R, rare-earth metal) family of materials. We use neutron scattering to study the structural and magnetic phase transitions in CeFeAsO(1-x)F(x) as the system is tuned from a semimetal to a high-Tc superconductor through fluorine (F) doping, x. In the undoped state, CeFeAsO develops a structural lattice distortion followed by a collinear antiferromagnetic order with decreasing temperature. With increasing fluorine doping, the structural phase transition decreases gradually and vanishes within the superconductivity dome near x=0.10, whereas the antiferromagnetic order is suppressed before the appearance of superconductivity for x>0.06, resulting in an electronic phase diagram remarkably similar to that of the high-Tc copper oxides. Comparison of the structural evolution of CeFeAsO(1-x)F(x) with other Fe-based superconductors suggests that the structural perfection of the Fe-As tetrahedron is important for the high-Tc superconductivity in these Fe pnictides.[Abstract] [Full Text] [Related] [New Search]