These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Extraction-spectrophotometric determination of vanadium with 3,5-dinitrocatechol and Brilliant Green.
    Author: Marczenko Z, Lobiński R.
    Journal: Talanta; 1988 Dec; 35(12):1001-4. PubMed ID: 18964663.
    Abstract:
    The formation and extraction of the ion-associates of the vanadium(V)-3,5-dinitrocatechol (DNC) anionic chelate complex with various basic dyes have been studied and a new sensitive extraction-spectrophotometric method for the determination of vanadium based on the system V(V)-DNC-Brilliant Green has been developed. Beer's law is obeyed up to a vanadium concentration of 0.3 mug/ml and the molar absorptivity is 1.7 x 1O(5) l.mole(-1). cm(-1) at 630 nm. The molar ratios of the components and the form of the vanadium(V) cation in the extracted compound have been determined, and the formula [VO(OH)(DNC)(2-)(2)][BG(+)](2) is proposed. Titanium, molybdenum, tungsten, EDTA and thiocyanate interfere seriously. The method becomes specific after a preliminary separation of vanadium by its extraction as the BPHA complex from H(2)SO(4)-HF medium, and is 40 times more sensitive than the spectrophotometric BPHA method. The proposed method has been applied to determination of traces of vanadium (about 10(-5)%) in alums.
    [Abstract] [Full Text] [Related] [New Search]