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  • Title: Direct catalytic asymmetric synthesis of cyclic aminals from aldehydes.
    Author: Cheng X, Vellalath S, Goddard R, List B.
    Journal: J Am Chem Soc; 2008 Nov 26; 130(47):15786-7. PubMed ID: 18975905.
    Abstract:
    A highly enantioselective Brønsted acid catalyzed direct synthesis of cyclic aminals from aldehydes has been developed. The methodology has been applied to the first asymmetric synthesis of several antihypertensive aminal drugs including (R)-Thiabutazide.
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