These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Further investigation of the effect of framework catenation on hydrogen uptake in metal-organic frameworks.
    Author: Ma S, Eckert J, Forster PM, Yoon JW, Hwang YK, Chang JS, Collier CD, Parise JB, Zhou HC.
    Journal: J Am Chem Soc; 2008 Nov 26; 130(47):15896-902. PubMed ID: 18980307.
    Abstract:
    Hydrogen-sorption studies have been carried out for the catenation isomer pairs of PCN-6 and PCN-6' (both have the formula of Cu(3)(TATB)(2), where TATB represents 4,4',4''-s-triazine-2,4,6-triyl-tribenzoate with a formula of C(24)H(12)N(3)O(6)). Inelastic neutron scattering (INS) studies reveal that the initial sites occupied by adsorbed H(2) are the open Cu centers of the paddlewheel units with comparable interaction energies in the two isomers. At high H(2) loadings, where the H(2) molecules adsorb mainly on or around the organic linkers, the interaction is found to be substantially stronger in catenated PCN-6 than in noncatenated PCN-6', leading to much higher H(2) uptake in the isomer with catenation. Hydrogen sorption measurements at pressures up to 50 bar demonstrate that framework catenation can be favorable for the enhancement of hydrogen adsorption. For example, the excess hydrogen uptake of PCN-6 is 72 mg/g (6.7 wt %) at 77 K/50 bar or 9.3 mg/g (0.92 wt %) at 298 K/50 bar, respectively, and that for PCN-6' is 42 mg/g (4.0 wt %) at 77 K/50 bar or 4.0 mg/g (0.40 wt %) at 298 K/50 bar. Importantly, PCN-6 exhibits a total hydrogen uptake of 95 mg/g (8.7 wt %) (corresponding to a total volumetric value of 53.0 g/L, estimated based on crystallographic density) at 77 K/50 bar and 15 mg/g (1.5 wt %) at 298 K/50 bar. Significantly, the expected usable capacity of PCN-6 is as high as 75 mg/g (or 41.9 g/L) at 77 K, if a recharging pressure of 1.5 bar is assumed.
    [Abstract] [Full Text] [Related] [New Search]