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  • Title: Highly enantioselective carbon-carbon bond formation by Cu-catalyzed asymmetric [2,3]-sigmatropic rearrangement: application to the syntheses of seven-membered oxacycles and six-membered carbocycles.
    Author: Kumaraswamy G, Sadaiah K, Ramakrishna DS, Police N, Sridhar B, Bharatam J.
    Journal: Chem Commun (Camb); 2008 Nov 14; (42):5324-6. PubMed ID: 18985198.
    Abstract:
    A concise route for the syntheses of enantioenriched functionalized scaffolds of medium-sized oxacycles and carbocycles employing the chiral auxiliary-mediated Cu-catalyzed ylide formation/[2,3]-sigmatropic rearrangement as a key step was developed.
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