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  • Title: Stereoselective rhodium-catalyzed imination of sulfides.
    Author: Collet F, Dodd RH, Dauban P.
    Journal: Org Lett; 2008 Dec 04; 10(23):5473-6. PubMed ID: 18986154.
    Abstract:
    The preparation of optically active sulfilimines via the catalytic diastereoselective imination of sulfides using a chiral nitrene is described. Excellent yields up to 97% and good diastereoselectivities up to 96% have been obtained. Oxidation of the sulfilimines then stereospecifically affords the corresponding sulfoximines with very good yields in the 88-96% range.
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