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  • Title: Thermodynamics of solution in liquid crystalline poly(propyleneimine) dendrimers by inverse gas chromatography.
    Author: Blokhina SV, Usol'tseva NV, Ol'khovich MV, Sharapova AV.
    Journal: J Chromatogr A; 2008 Dec 26; 1215(1-2):161-7. PubMed ID: 19026424.
    Abstract:
    Thermodynamic characteristics of infinitely diluted solutions of n-alkanes and n-alcohols in the columnar and isotropic phases of poly(propyleneimine) dendrimers, generations 1-3 (G1-G3), have been investigated by inverse gas chromatography (IGC). Effects of the dendrimer structure, the chemical nature and molecular size of the non-mesogenes on the ability to get dissolved in the liquid crystalline phases are discussed. The compatibility of the low-molecular compounds with the anisotropic phases is stated to increase with generation G.
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