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  • Title: Electro-fluorescence switching of bis-imidazolium ionic liquids.
    Author: Lee WR, Kim Y, Kim JY, Kim TH, Ahn KD, Kim E.
    Journal: J Nanosci Nanotechnol; 2008 Sep; 8(9):4630-4. PubMed ID: 19049073.
    Abstract:
    Room-temperature ionic liquids (RTILs) containing bis-imidazolium salts were explored to control their optical properties of them in an organic device. The neat bis-imidazolium salts showed ionic conductivity of 3.5 x 10(-4) S/cm at room-temperature and the electrochemical window was exhibited within +/-2.5 V in a two electrode cell. The bis-imidazolium salts were transparent yellow and showed fluorescence upon excitation with light in the range of 360 to 500 nm. A two electrode organic ionic liquid cell was fabricated using a mixture of PEO200Blm-TFSI and electroactive molecules to control the emission property of the ionic liquid by electrochemical methods. The first example of the ionic liquid containing electro-fluorescence switch was explored with an electroactive benzyl viologen (BzV) blend of bis-imidazolium ionic liquid.
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