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  • Title: Catalytic enantioselective intermolecular hydroacylation: rhodium-catalyzed combination of beta-S-aldehydes and 1,3-disubstituted allenes.
    Author: Osborne JD, Randell-Sly HE, Currie GS, Cowley AR, Willis MC.
    Journal: J Am Chem Soc; 2008 Dec 24; 130(51):17232-3. PubMed ID: 19053453.
    Abstract:
    A rhodium(I) catalyst incorporating the Me-DuPhos ligand promotes enantioselective intermolecular hydroacylation between beta-S-aldehydes and 1,3-disubstituted allenes. The nonconjugated enone products are obtained in good yields and with high enantioselectivities.
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