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  • Title: Diphenylprolinol silyl ether catalysis in an asymmetric formal carbo [3 + 3] cycloaddition reaction via a domino Michael/Knoevenagel condensation.
    Author: Hayashi Y, Toyoshima M, Gotoh H, Ishikawa H.
    Journal: Org Lett; 2009 Jan 01; 11(1):45-8. PubMed ID: 19053718.
    Abstract:
    Diphenylprolinol silyl ether was found to catalyze the formal carbo [3 + 3] cycloaddition reaction through the domino reaction via the Michael reaction, followed by Knoevenagel condensation of the alpha,beta-unsaturated aldehyde and dimethyl 3-oxopentanedioate, affording substituted cyclohexenone derivatives with excellent enantioselectivity.
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