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  • Title: Homologation of boronic esters with lithiated epoxides for the stereocontrolled synthesis of 1,2- and 1,3-diols and 1,2,4-triols.
    Author: Vedrenne E, Wallner OA, Vitale M, Schmidt F, Aggarwal VK.
    Journal: Org Lett; 2009 Jan 01; 11(1):165-8. PubMed ID: 19067552.
    Abstract:
    Lithiated epoxides react stereospecifically with boronic esters to give syn-1,2-diols, a process that can be used iteratively to create triols containing four stereogenic centers.
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