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  • Title: Stable preformed chiral palladium catalysts for the one-pot asymmetric reductive amination of ketones.
    Author: Rubio-Pérez L, Pérez-Flores FJ, Sharma P, Velasco L, Cabrera A.
    Journal: Org Lett; 2009 Jan 15; 11(2):265-8. PubMed ID: 19093803.
    Abstract:
    The application of air stable preformed [(R)-BINAP]PdBr2, [(S)-BINAP]PdBr2, [(R)-Tol-BINAP]PdBr2, and [(S,S)-CHIRAPHOS]PdBr2 complexes in the one-pot asymmetric reductive amination of various carbonyl compounds, leading to chiral amines in very good yields with high enantioselectivities (<99% ee), is reported.
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