These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Si-based benzylic 1,4-rearrangement/cyclization reaction.
    Author: Trost BM, Bertogg A.
    Journal: Org Lett; 2009 Feb 05; 11(3):511-3. PubMed ID: 19125665.
    Abstract:
    The trans-selective hydrosilylation of ynones (1) yields beta-silylated enones (2) that undergo a benzylic 1,4-rearrangement/cyclization reaction in the presence of base, yielding 2,5-dihydro-1,2-oxasiloles (3).
    [Abstract] [Full Text] [Related] [New Search]