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Title: Highly fluorescent rigid supramolecular polymeric nanowires constructed through multiple hydrogen bonds. Author: Luo J, Lei T, Wang L, Ma Y, Cao Y, Wang J, Pei J. Journal: J Am Chem Soc; 2009 Feb 18; 131(6):2076-7. PubMed ID: 19159299. Abstract: Supramolecular polymeric nanowires 1(n) constructed by a 3D shape-persistent hexaacid 1 through multiple hydrogen bonding interactions was developed. Single molecular nanoires were also obtained from its highly dilute solution.Hexaacid 1 containing pi-conjugated chromophores successfully self-assembled to afford these nanofibers with high solid quantum efficiency (22%), which provides us a pathway to fabricate optoelectronic devices using these highly fluorescent nanofibers.[Abstract] [Full Text] [Related] [New Search]