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  • Title: Facile synthesis of highly stable gold nanoparticles and their unexpected excellent catalytic activity for Suzuki-Miyaura cross-coupling reaction in water.
    Author: Han J, Liu Y, Guo R.
    Journal: J Am Chem Soc; 2009 Feb 18; 131(6):2060-1. PubMed ID: 19170490.
    Abstract:
    We have demonstrated that poly(2-aminothiophenol)-stablized gold nanoparticles with proper gold size and polymer thickness are active catalysts for Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids in water and air for the first time. High yields can be obtained with aryl halides or arylboronic acids bearing a variety of substituents. This new finding will undoubtedly broaden the application of gold nanoparticles in organic catalytic reactions.
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