These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Octylglucopyranoside and cyclodextrin in water. Self-aggregation and complex formation.
    Author: Haller J, Kaatze U.
    Journal: J Phys Chem B; 2009 Feb 19; 113(7):1940-7. PubMed ID: 19170546.
    Abstract:
    At 25 degrees C ultrasonic attenuation spectra between 100 kHz and 400 MHz as well as sound velocities and densities of aqueous solutions of the surfactant n-octyl-beta-d-glucopyranoside and of the cage compound alpha-cyclodextrin have been measured. The liquid system reveals a critical association concentration (cac) exceeding the cmc of the surfactant almost by the cyclodextrin concentration and thus indicating a significant formation of cyclodextrin-surfactant inclusion complexes. The ultrasonic spectra display altogether four relaxation regions. The one with largest relaxation time (0.27 mus < or = tau(1) < or = 1.6 mus) exhibits a noticeable amplitude at surfactant concentrations larger than the cac only. It is assigned to the monomer exchange between the micelles and the suspending phase. A term with relaxation time tau(2) (33 ns < or = tau(2) < or = 135 ns) is characteristic for solutions containing both solutes. It is assumed to reflect the inclusion complex formation. Complexes with 1:1, 2:1, and 1:2 stoichiometry appear to exist. The terms at higher frequencies (4.8 ns < or = tau(3) < or = 9.8 ns; 0.8 ns <or = tau(4) < or = 2 ns) are due to fluctuations of the carbohydrate residues around the glucosidic bond angles and to the rotational isomerization of the exocyclic hydroxymethyl groups, respectively.
    [Abstract] [Full Text] [Related] [New Search]