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  • Title: Chemo- and regioselective palladium-catalyzed oxycyclization reactions of allendiols: preparation of five-, six-, and eight-membered cycles.
    Author: Alcaide B, Almendros P, Carrascosa R, Martínez del Campo T.
    Journal: Chemistry; 2009 Mar 02; 15(11):2496-9. PubMed ID: 19185045.
    Abstract:
    Positive discrimination: Chemo- and regioselective palladium-catalyzed cycloetherification of allendiols, namely beta,gamma- and gamma,delta-allendiols, may occur by judicious choice of palladium-catalyzed conditions owing to their potential ability to discriminate between both nucleophilic sites (see scheme).
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