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Title: Evaluation of soil pH and moisture content on in-situ ozonation of pyrene in soils. Author: Luster-Teasley S, Ubaka-Blackmoore N, Masten SJ. Journal: J Hazard Mater; 2009 Aug 15; 167(1-3):701-6. PubMed ID: 19223120. Abstract: In this study, pyrene spiked soil (300 ppm) was ozonated at pH levels of 2, 6, and 8 and three moisture contents. It was found that soil pH and moisture content impacted the effectiveness of PAH oxidation in unsaturated soils. In air-dried soils, as pH increased, removal increased, such that pyrene removal efficiencies at pH 6 and pH 8 reached 95-97% at a dose of 2.22 mg O(3)/mg pyrene. Ozonation at 16.2+/-0.45 mg O(3)/ppm pyrene in soil resulted in 81-98% removal of pyrene at all pH levels tested. Saturated soils were tested at dry, 5% or 10% moisture conditions. The removal of pyrene was slower in moisturized soils, with the efficiency decreasing as the moisture content increased. Increasing the pH of the soil having a moisture content of 5% resulted in improved pyrene removals. On the contrary, in the soil having a moisture content of 10%, as the pH increased, pyrene removal decreased. Contaminated PAH soils were stored for 6 months to compare the efficiency of PAH removal in freshly contaminated soil and aged soils. PAH adsorption to soil was found to increase with longer exposure times; thus requiring much higher doses of ozone to effectively oxidize pyrene.[Abstract] [Full Text] [Related] [New Search]