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  • Title: A new route for substitution of the bridging acetate on the oxo-centered triruthenium acetate cluster.
    Author: Yuge H, Asahi S, Miyamoto TK.
    Journal: Dalton Trans; 2009 Apr 07; (13):2287-9. PubMed ID: 19290360.
    Abstract:
    Deacetoxylation of the oxo-centered triruthenium acetate cluster by acetyl chloride or triethylsilyl chloride led to the formation of a versatile precursor [Ru(3)O(OAc)(5)(Cl)(4-methylpyridine)(2)(CNt-Bu)], whose chloro ligand was readily substituted by other bridging ligands, i.e. alkoxides, carboxylates or sulfides.
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