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  • Title: Syntheses and structures of phenyl-C81-butyric acid methyl esters (PCBMs) from M3N@C80.
    Author: Shu C, Xu W, Slebodnick C, Champion H, Fu W, Reid JE, Azurmendi H, Wang C, Harich K, Dorn HC, Gibson HW.
    Journal: Org Lett; 2009 Apr 16; 11(8):1753-6. PubMed ID: 19309087.
    Abstract:
    Two new 6,6-open phenyl-C(81)-butyric acid methyl ester metallofulleroids, M(3)N@C(80)PCBM (M = Sc, Y), were synthesized by diazoalkane addition reactions and fully characterized. The results demonstrate that the reactive sites are the same for M(3)N@C(80) (M = Sc, Y) but dramatically different from that of C(60).
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