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  • Title: Alpha-zirconium phosphonates: versatile supports for N-heterocyclic carbenes.
    Author: Chessa S, Clayden NJ, Bochmann M, Wright JA.
    Journal: Chem Commun (Camb); 2009 Feb 21; (7):797-9. PubMed ID: 19322445.
    Abstract:
    alpha-Zirconium phosphonates derivatised with N-heterocyclic carbenes provide a versatile platform for organocatalysis and metal-catalysed transformations, including the ring-opening polymerisation of cyclic esters, and olefin metathesis and hydroformylations by surface-bound ruthenium, rhodium and iridium complexes.
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