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  • Title: Stereoselective synthesis of amphidinolide T1.
    Author: Yadav JS, Reddy ChS.
    Journal: Org Lett; 2009 Apr 16; 11(8):1705-8. PubMed ID: 19323491.
    Abstract:
    A highly stereoselective total synthesis of amphidinolide T1 is achieved using Sharpless asymmetric epoxidation, base-induced epoxide opening, radical cyclization, diastereoselective reduction followed by allylation, Evans methylation, base-induced reductive elimination, umpolung reaction, chemoselective oxidation, and regioselective macrolactonization.
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