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  • Title: Phosphoramidite accelerated copper(i)-catalyzed [3 + 2] cycloadditions of azides and alkynes.
    Author: Campbell-Verduyn LS, Mirfeizi L, Dierckx RA, Elsinga PH, Feringa BL.
    Journal: Chem Commun (Camb); 2009 Apr 28; (16):2139-41. PubMed ID: 19360172.
    Abstract:
    Monodentate phosphoramidite ligands are used to accelerate the copper(i)-catalyzed 1,3-dipolar cycloaddition of azides and alkynes (CuAAC) rapidly yielding a wide variety of functionalized 1,4-disubstituted-1,2,3-triazoles; Cu(i) and Cu(ii) salts both function as the copper source in aqueous solution to provide excellent yields.
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