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  • Title: Iron-catalyzed asymmetric aerobic oxidation: oxidative coupling of 2-naphthols.
    Author: Egami H, Katsuki T.
    Journal: J Am Chem Soc; 2009 May 06; 131(17):6082-3. PubMed ID: 19361160.
    Abstract:
    Fe(salan) complexes were found to be efficient catalysts for the asymmetric aerobic oxidative coupling of 2-naphthol derivatives. This reaction can be carried out in air at 60 degrees C with high enantioselectivity up to 97% ee. This is the first report for asymmetric aerobic oxidation using molecular oxygen in air in the absence of additives.
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