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Title: Biphenylene-substituted ruthenocenylphosphine for Suzuki-Miyaura coupling of sterically hindered aryl bromides. Author: Hoshi T, Saitoh I, Nakazawa T, Suzuki T, Sakai J, Hagiwara H. Journal: J Org Chem; 2009 May 15; 74(10):4013-6. PubMed ID: 19391580. Abstract: A highly general, active, and stable catalytic system was realized in the palladium-catalyzed Suzuki-Miyaura reactions of sterically hindered aryl bromides with arylboronic acids using biphenylene-substituted di-tert-butylruthenocenylphosphine (R-Phos) as a supporting ligand.[Abstract] [Full Text] [Related] [New Search]