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  • Title: Sulfonamido-phosphoramidite ligands in cooperative dinuclear hydrogenation catalysis.
    Author: Patureau FW, de Boer S, Kuil M, Meeuwissen J, Breuil PA, Siegler MA, Spek AL, Sandee AJ, de Bruin B, Reek JN.
    Journal: J Am Chem Soc; 2009 May 20; 131(19):6683-5. PubMed ID: 19397373.
    Abstract:
    Sulfonamido-phosphoramidite ligands lead to the formation of Rh-Rh dinuclear complexes through the anionic P-N(-) bridging character. The resulting "boat-shaped" dinuclear catalysts activate molecular H(2) through a cooperative dinuclear endocyclic mechanism, resulting in one bridging and one classical hydride on the dinuclear complex. These new complexes are very active hydrogenation catalysts that operate via a new cooperative hydrogenation activation mechanism, as calculated with density functional theory, and they display unequaled high selectivities in the hydrogenation of hindered cyclic acetamidoalkenes.
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