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  • Title: Palladium-catalyzed decarboxylative coupling of allylic alkynoates with arynes.
    Author: Pi SF, Tang BX, Li JH, Liu YL, Liang Y.
    Journal: Org Lett; 2009 Jun 04; 11(11):2309-12. PubMed ID: 19402675.
    Abstract:
    A novel and selective protocol for the synthesis of 1-allyl-2-ethynylbenzenes has been developed by palladium-catalyzed decarboxylative coupling of allylic alkynoates with arynes. This new route allows for both sp-sp(2) and sp(2)-sp(3) couplings of allylic alkynoates with arynes in one pot involving a decarboxylation process.
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