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  • Title: Stereoselective asymmetric synthesis of (+)-sedamine and (+)-allosedamine.
    Author: Lebrun S, Couture A, Deniau E, Grandclaudon P.
    Journal: Chirality; 2010 Feb; 22(2):212-6. PubMed ID: 19418554.
    Abstract:
    A convenient method for the generation of (+)-sedamine and (+)-allosedamine in high optical purity has been elaborated. The key steps are the highly stereoselective 1,2-nucleophilic addition to SAMP hydrazones allowing the installation of the stereogenic center at C2 and ring closing metathesis.
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