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  • Title: Synthetic method for the preparation of 2-aminomethyl-1,3-diene derivatives through indium-mediated 1,3-butadien-2-ylation of imines.
    Author: Seomoon D, A J, Lee PH.
    Journal: Org Lett; 2009 Jun 04; 11(11):2401-4. PubMed ID: 19422264.
    Abstract:
    An efficient method for the preparation of a variety of 2-aminomethyl-1,3-dienes was developed through the reaction of imines with organoindium reagent generated in situ from indium and 1,3-dibromo-2-butyne. Three-component reactions of aldehydes, amines, and organoindium reagents gave successful results in a one-pot process.
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