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  • Title: Efficient and economical access to substituted benzothiazoles: copper-catalyzed coupling of 2-haloanilides with metal sulfides and subsequent condensation.
    Author: Ma D, Xie S, Xue P, Zhang X, Dong J, Jiang Y.
    Journal: Angew Chem Int Ed Engl; 2009; 48(23):4222-5. PubMed ID: 19425042.
    Abstract:
    Don't tell azole: The first metal-catalyzed direct coupling of metal sulfides with aryl halides and subsequent intramolecular condensation provided substituted benzothiazoles (see scheme). A wide range of functional groups are tolerated under the reaction conditions.
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