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  • Title: Daphenylline, a new alkaloid with an unusual skeleton, from Daphniphyllum longeracemosum.
    Author: Zhang Q, Di YT, Li CS, Fang X, Tan CJ, Zhang Z, Zhang Y, He HP, Li SL, Hao XJ.
    Journal: Org Lett; 2009 Jun 04; 11(11):2357-9. PubMed ID: 19438261.
    Abstract:
    A new alkaloid, daphenylline (1), with an unprecedented rearranged 22-nor-calyciphylline skeleton, was isolated from the fruits of Daphniphyllum longeracemosum. Its structure and stereochemistry were elucidated on the basis of spectroscopic and computational approaches. A plausible biosynthetic pathway of 1 was also proposed.
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