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  • Title: Tandem alkylation-Michael addition to vinylogous carbonates for the stereoselective construction of 2,3,3,6-tetrasubstituted tetrahydropyrans.
    Author: Gharpure SJ, Reddy SR.
    Journal: Org Lett; 2009 Jun 18; 11(12):2519-22. PubMed ID: 19445488.
    Abstract:
    A stereoselective method for the synthesis of substituted tetrahydropyran derivatives employing a tandem S(N)2-Michael addition sequence to vinylogous carbonates is developed. The method is extended to the synthesis of bicyclic ether motifs present in polyether ladder toxins.
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