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  • Title: A highly enantioselective allylic amination reaction using a commercially available chiral rhodium catalyst: resolution of racemic allylic carbonates.
    Author: Vrieze DC, Hoge GS, Hoerter PZ, Van Haitsma JT, Samas BM.
    Journal: Org Lett; 2009 Jul 16; 11(14):3140-2. PubMed ID: 19527001.
    Abstract:
    A novel method for the kinetic resolution of unsymmetrical acyclic allylic carbonates and the concurrent synthesis of enantioenriched secondary amines using a commercially available chiral catalyst is disclosed.
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