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  • Title: A stereoselective synthesis of (+)-physoperuvine using a tandem aza-Claisen rearrangement and ring closing metathesis reaction.
    Author: Zaed AM, Swift MD, Sutherland A.
    Journal: Org Biomol Chem; 2009 Jul 07; 7(13):2678-80. PubMed ID: 19532981.
    Abstract:
    A stereoselective synthesis of (+)-physoperuvine, a tropane alkaloid from Physalis peruviana Linne has been developed using a one-pot tandem aza-Claisen rearrangement and ring closing metathesis reaction to form the key amino-substituted cycloheptene ring.
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