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  • Title: Library assembly of mono-, di- and tri-O-sulfated beta-D-xylopyranosides; effect of O-sulfation on pyranose ring conformation.
    Author: Nagatsuka T, Uzawa H, Nishida Y.
    Journal: Chem Commun (Camb); 2009 Jul 21; (27):4109-11. PubMed ID: 19568649.
    Abstract:
    With molluscan sulfatase-catalyzed de-O-sulfation reactions, a series of mono-, di- and tri-O-sulfated p-nitrophenyl beta-D-xylopyranosides were assembled and applied to a 1H NMR study to examine the effect of O-sulfate groups on the equilibration between pyranose 4C1 and 1C4 conformations.
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