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  • Title: Pd(0)/PR3-catalyzed intermolecular arylation of sp3 C-H bonds.
    Author: Wasa M, Engle KM, Yu JQ.
    Journal: J Am Chem Soc; 2009 Jul 29; 131(29):9886-7. PubMed ID: 19580277.
    Abstract:
    Pd(0)-catalyzed intermolecular arylation of sp(3) C-H bonds has been achieved using PR(3)/ArI. This protocol can be used to arylate a variety of aliphatic carboxylic acid derivatives, including a number of bioactive drug molecules. The use of fluorinated aryl iodides also allows for the introduction of fluorine into a molecule of interest.
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