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  • Title: Highly enantioselective organocatalytic Michael addition of nitroalkanes to 4-oxo-enoates.
    Author: Lu HH, Wang XF, Yao CJ, Zhang JM, Wu H, Xiao WJ.
    Journal: Chem Commun (Camb); 2009 Jul 28; (28):4251-3. PubMed ID: 19585037.
    Abstract:
    A useful Michael addition reaction using nitroalkanes as the nucleophile and 4-oxo-enoates as the Michael acceptor has been disclosed, and the reaction allows expedient access to functionalized chiral gamma-keto esters in high yields and excellent enantioselectivities (up to 98% ee), with a low catalyst loading.
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