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  • Title: Asymmetric Friedel-Crafts reaction of N-heterocycles and nitroalkenes catalyzed by imidazoline-aminophenol-Cu complex.
    Author: Yokoyama N, Arai T.
    Journal: Chem Commun (Camb); 2009 Jun 14; (22):3285-7. PubMed ID: 19587941.
    Abstract:
    Catalytic asymmetric Friedel-Crafts reaction of pyrrole with nitroalkenes was smoothly catalyzed by newly synthesized nitro-substituted imidazoline-aminophenol (1b)-Cu complex to give the adduct with up to 92% ee.
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