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Title: Ultrasensitive detection of nitric oxide at 5.33 microm by using external cavity quantum cascade laser-based Faraday rotation spectroscopy. Author: Lewicki R, Doty JH, Curl RF, Tittel FK, Wysocki G. Journal: Proc Natl Acad Sci U S A; 2009 Aug 04; 106(31):12587-92. PubMed ID: 19625625. Abstract: A transportable prototype Faraday rotation spectroscopic system based on a tunable external cavity quantum cascade laser has been developed for ultrasensitive detection of nitric oxide (NO). A broadly tunable laser source allows targeting the optimum Q(3/2)(3/2) molecular transition at 1875.81 cm(-1) of the NO fundamental band. For an active optical path of 44 cm and 1-s lock-in time constant minimum NO detection limits (1sigma) of 4.3 parts per billion by volume (ppbv) and 0.38 ppbv are obtained by using a thermoelectrically cooled mercury-cadmium-telluride photodetector and liquid nitrogen-cooled indium-antimonide photodetector, respectively. Laboratory performance evaluation and results of continuous, unattended monitoring of atmospheric NO concentration levels are reported.[Abstract] [Full Text] [Related] [New Search]