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  • Title: Palladium-catalysed enantioselective alpha-hydroxylation of beta-ketoesters.
    Author: Smith AM, Billen D, Hii KK.
    Journal: Chem Commun (Camb); 2009 Jul 14; (26):3925-7. PubMed ID: 19662254.
    Abstract:
    Highly enantioselective alpha-hydroxylation of cyclic and acyclic 1,3-ketoesters can be achieved with up to 98% ee using a dicationic palladium(ii) catalyst and dimethyldioxirane as oxidant.
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