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  • Title: Cross-cyclotrimerization with two nitriles as a synthetic pathway to unsymmetrically 3,3'-disubstituted bis(tetrahydroisoquinolines).
    Author: Kadlcíková A, Kotora M.
    Journal: Molecules; 2009 Aug 10; 14(8):2918-26. PubMed ID: 19701134.
    Abstract:
    Microwave assisted CpCo(CO)(2) catalyzed cross-cyclotrimerizations of 1,7,9,15-hexadecatetrayne with two different nitriles to give unsymmetrically substituted bis(tetrahydroisoquinolines) was studied. The reaction proceeded with a range of alkyl and aryl nitriles with reasonable isolated yields.
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