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  • Title: Iridium-catalyzed coupling reaction of primary alcohols with 1-aryl-1-propynes leading to secondary homoallylic alcohols.
    Author: Obora Y, Hatanaka S, Ishii Y.
    Journal: Org Lett; 2009 Aug 06; 11(15):3510-3. PubMed ID: 19719194.
    Abstract:
    We report iridium-catalyzed coupling of 2-alkynes such as 1-aryl-1-propynes with primary alcohols leading to secondary homoallylic alcohols as products. This reaction involves an iridium-catalyzed novel catalytic transformation of 2-alkynes and primary alcohols through the formation of hydrido(pi-allyl)iridium as a possible key intermediate.
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